The comparison of free hole concentrations in p-type semiconductors ob
tained by Raman and by Hall measurements gives the possibility of dete
rmining an effective Hall factor depending on temperature and hole con
centration. This will be shown for GaAs, GaP and InP in the temperatur
e range from 77 K to 300 K. In the case of GaAs the experimentally obt
ained Hall factor is compared with a theoretical one, calculated from
different scattering mechanisms within a two-band model. For the evalu
ation of Raman measurements a generalization of the Drude theory inclu
ding interband transitions is used. Theoretical Hall factors and the c
omparison of calculated Hall mobilities with experimental ones are giv
en. Possible sources of errors in the theory and in the evaluation of
the experimental results are discussed.