Ym. Yarmoshenko et al., OBSERVATION OF MAGNETIC SPLITTING IN XPS MNL-SPECTRA OF CO2MNSN AND PD2MNSN HEUSLER ALLOYS, EUROPEAN PHYSICAL JOURNAL B, 2(1), 1998, pp. 1-3
The XPS MnL-spectra of Co2MnSn, a nearly half-metallic ferromagnet (HM
F) and Pd2MnSn were investigated. The most drastical feature of the sp
ectra observed is the well-defined magnetic splitting of the Mn 2p(3/2
), 2p(1/2) lines. This gives direct evidence of the existence of well-
defined local magnetic moments in Heusler alloys in comparison with ot
her itinerant-electron ferromagnets. The calculations of Mn2p XPS spec
tra of these materials were carried out using a fully relativistic gen
eralization of the one-step model of photoemission and show excellent
agreement with experiment.