Two new sets of QCD sum rules for the nucleon axial-vector coupling co
nstants are derived using the external-field technique and generalized
interpolating fields. An in-depth study of the predicative ability of
these sum rules is carried out using a Monte Carlo-based uncertainty
analysis. The results show that the standard implementation of the QCD
sum rule method has only marginal predicative power Tor the nucleon a
xial-vector coupling constants, as the relative errors are large. The
errors range from approximately 50% to 100% compared to the nucleon ma
ss obtained from the same method, which has only a 10%-25% error. The
origin of the large errors is examined. Previous analyses of these cou
pling constants are based on sum rules that have poor operator product
expansion convergence and large continuum contributions, Preferred su
m rules are identified and their predictions are obtained. We also inv
estigate the new sum rules with an alternative treatment of the proble
matic transitions which are not exponentially suppressed in the standa
rd treatment. The alternative treatment provides exponential suppressi
on of their contributions relative to the ground state. Implications f
or other nucleon current matrix elements are also discussed.