Gas chromatography coupled with Fourier transform infrared spectrometr
y differentiates fatty acid methyl ester geometric isomers. The spectr
a of mono- and di-unsaturated compounds exhibited cis (Z) and trans (E
) specific bands. Cyclic fatty acid monomers showed characteristic spe
ctra of the ring structure. The spectra acquired with both the light-p
ipe and the direct deposition interfaces showed significant difference
s due to the respective vapour and condensed phases used in the system
s.