THE STRUCTURE OF HYDROTRIS(PYRAZOLYL)BORATOTHALLIUM(I)

Citation
C. Janiak et al., THE STRUCTURE OF HYDROTRIS(PYRAZOLYL)BORATOTHALLIUM(I), Zeitschrift fur anorganische und allgemeine Chemie, 624(5), 1998, pp. 755-756
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
5
Year of publication
1998
Pages
755 - 756
Database
ISI
SICI code
0044-2313(1998)624:5<755:TSOH>2.0.ZU;2-6
Abstract
The title compound crystallizes in the monoclinic space group P2(1) wi th a=7.928(6), b=9.306(4), c=17.16(2)Angstrom, beta=92.06(8)degrees, V =1265(2)Angstrom(3), Z=2, D-calc= 2.191 g cm(-3). From two independent molecular units, metal-ligand strands are formed based on electrostat ic interactions between the thallium centers and pyrazolyl pi manifold s from neighboring molecules.