PREPARATION AND CRYSTAL-STRUCTURE OF CS4S NO3

Authors
ROHR C ZONNCHEN P
Citation
C. Rohr et P. Zonnchen, PREPARATION AND CRYSTAL-STRUCTURE OF CS4S NO3, Zeitschrift fur anorganische und allgemeine Chemie, 624(5), 1998, pp. 797-801
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
5
Year of publication
1998
Pages
797 - 801
Database
ISI
SICI code
0044-2313(1998)624:5<797:PACOCN>2.0.ZU;2-Y
Abstract
Crystals of Cs4SnO3 were synthesized by reaction of SnO with elemental Cs. The compound crystallizes with the triclinic spacegroup P (1) ove r bar with lattice constants a = 737.61(9) pm, b = 1171.3(1) pm, c = 1 199.2(1) pm, alpha = 66.08(3)degrees, beta = 80.88(2)degrees, gamma = 82.28(3)degrees and Z = 4. The crystal structure exhibits isolated sta nnate(II) ions [(SnO3)-O-II](4-) of psi-tetrahedral form. Whereas a ne w structure type is present, there is a close relationship with the st ructures of the Cs stanntates and plumbates(IV).