A STRUCTURAL COMPARISON OF DONOR-STABILIZ ED ALUMINUM-IODIDES

Authors
ECKER A SCHNOCKEL H
Citation
A. Ecker et H. Schnockel, A STRUCTURAL COMPARISON OF DONOR-STABILIZ ED ALUMINUM-IODIDES, Zeitschrift fur anorganische und allgemeine Chemie, 624(5), 1998, pp. 813-816
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
5
Year of publication
1998
Pages
813 - 816
Database
ISI
SICI code
0044-2313(1998)624:5<813:ASCODE>2.0.ZU;2-B
Abstract
In order to compare aluminium-iodides in different oxidation states th e following species containing identical donor ligands have been synth esized: Al4I4 . 4PEt(3) and AlI3 . 2PEt(3). Their structural data are compared with those of the recently prepared Al2I4 . 2PEt(3). In spite of different coordination numbers (4 and 5) the expected trends in th e size of Al-I, A(II) and Al-III and of their bonding to iodine and PE t3 could be realized.