We present results on the optical characterization of InxGa1-xP layers
grown by atomic layer molecular beam epitaxy on GaAs (001) substrates
at a growth temperature of 420 degrees C. Our results show that the o
ptical characteristics of these layers, which do not show ordering eff
ects, are strongly dependent on surface stoichiometry during growth. I
n this way, we can obtain either highly homogeneous alloys with a pred
ictable band-gap energy or layers with optical properties indicative o
f spatial localization effects, like an anomalous behavior of photolum
inescence peak energy with temperature and a large shift between the e
mission energy and absorption edge. (C) 1998 American Institute of Phy
sics.