Ms. Uretazanartu et al., ELECTRODEPOSITED PT-IR ELECTRODES - CHARACTERIZATION AND ELECTROCATALYTIC ACTIVITY FOR THE REDUCTION OF THE NITRATE ION, JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2(3), 1998, pp. 191-197
The activity of Pt-Ir deposits on titanium for the reduction of the ni
trate ion in 0.5 M perchloric acid was studied. The electrodes were ch
aracterized by SEM-EDAX, XPS and cyclic voltammetry. The activity of t
he electrodes for the nitrate reduction depended on the Pt-Ir ratio. R
epetitive cyclic voltammograms produced an enrichment of the electrode
surface with Ir and a decrease of the catalytic activity. A synergist
ic effect in the electrodes with low iridium content is discussed.