STRUCTURAL CHARACTERIZATION OF SOME NORTH-AMERICAN COALS

The structure of five U.S. coals (three of low rank or sub-bituminous and two of high rank) has been investigated using reactivity criteria and spectroscopic methods. The results suggest that one of the high-ra nk coals PSOC 831 contains more cross-linking groups within its macrom olecular structure than the other high-rank coal DECS 1.2. These cross -linkages help to explain some previously reported anomalous results r esulting from reactions of PSOC 831 with hydrogen in the presence of M oS2. The DECS 9 and PSOC 1379 were shown to be typical low-rank coals and gave significant ''guest''-derived materials (terpenoid and wax-de rived hydrocarbons) from pyrolyses at 320 and 350 degrees C, and the s ub-bituminous coal DECS 6 showed many structural similarities when com pared with a range of other sub-bituminous coals from Central Queensla nd, Australia.