SYNTHESIS, CRYSTAL-STRUCTURE AND SOLID-STATE DYNAMICS OF THE LA(HFA)(3)CENTER-DOT-ME(OCH2CH2)(4)OME (HHFA = 1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONE) PRECURSOR FOR MOCVD APPLICATIONS

Authors
MALANDRINO G FRAGALA IL AIME S DASTRU W GOBETTO R BENELLI C
Citation
G. Malandrino et al., SYNTHESIS, CRYSTAL-STRUCTURE AND SOLID-STATE DYNAMICS OF THE LA(HFA)(3)CENTER-DOT-ME(OCH2CH2)(4)OME (HHFA = 1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONE) PRECURSOR FOR MOCVD APPLICATIONS, Journal of the Chemical Society. Dalton transactions, (9), 1998, pp. 1509-1512
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
9
Year of publication
1998
Pages
1509 - 1512
Database
ISI
SICI code
0300-9246(1998):9<1509:SCASDO>2.0.ZU;2-M
Abstract
The reaction of La2O3 with 1,1,1,5,5,5-hexafluoropentane-2,4-dione (Hh fa) and tetraglyme [Me(OCH2CH2)(4)OMe] in hexane yielded the air stabl e, ten-co-ordinate La(hfa)(3) . Me(OCH2CH2)(4)OMe adduct. This new add uct represents a promising volatile lanthanum precursor for low-pressu re MOCVD applications. It displays a high volatility, which can be rel ated to a fast molecular reorientation in the solid state as establish ed by combined DSC, H-1 and C-13 NMR investigations.