ANALYZING MECHANISMS OF COMPLEX ELECTROCHEMICAL PROCESSES BY THE NETWORK THERMODYNAMICS METHOD - 2-ELECTRON MULTISTAGE REACTIONS OF THE FIRST AND 2ND-ORDER
Os. Ksenzhek et Sa. Petrova, ANALYZING MECHANISMS OF COMPLEX ELECTROCHEMICAL PROCESSES BY THE NETWORK THERMODYNAMICS METHOD - 2-ELECTRON MULTISTAGE REACTIONS OF THE FIRST AND 2ND-ORDER, Russian journal of electrochemistry, 33(4), 1997, pp. 447-451
The network thermodynamics method is used to consider a two-electron m
ultistage reaction of the first order (the EE mechanism) and a more co
mplex reaction involving a stage where a dimer of an intermediate reac
tion product (semiquinone) is formed. Bond graphs are plotted for thes
e processes, and analytical expressions are obtained for the system ad
mittance.