ANALYZING MECHANISMS OF COMPLEX ELECTROCHEMICAL PROCESSES BY THE NETWORK THERMODYNAMICS METHOD - 2-ELECTRON MULTISTAGE REACTIONS OF THE FIRST AND 2ND-ORDER

Citation
Os. Ksenzhek et Sa. Petrova, ANALYZING MECHANISMS OF COMPLEX ELECTROCHEMICAL PROCESSES BY THE NETWORK THERMODYNAMICS METHOD - 2-ELECTRON MULTISTAGE REACTIONS OF THE FIRST AND 2ND-ORDER, Russian journal of electrochemistry, 33(4), 1997, pp. 447-451
Citations number
6
Categorie Soggetti
Electrochemistry
ISSN journal
10231935
Volume
33
Issue
4
Year of publication
1997
Pages
447 - 451
Database
ISI
SICI code
1023-1935(1997)33:4<447:AMOCEP>2.0.ZU;2-1
Abstract
The network thermodynamics method is used to consider a two-electron m ultistage reaction of the first order (the EE mechanism) and a more co mplex reaction involving a stage where a dimer of an intermediate reac tion product (semiquinone) is formed. Bond graphs are plotted for thes e processes, and analytical expressions are obtained for the system ad mittance.