ASYMPTOTICALLY MAXIMIN OBSERVATION OF TRACES OF CHEMICAL-ELEMENTS FROM ANALYTICAL SIGNALS OF INDUCTIVELY-COUPLED PLASMA-ATOMIC EMISSION-SPECTROMETRY

Citation
Gm. Bashin et At. Savichev, ASYMPTOTICALLY MAXIMIN OBSERVATION OF TRACES OF CHEMICAL-ELEMENTS FROM ANALYTICAL SIGNALS OF INDUCTIVELY-COUPLED PLASMA-ATOMIC EMISSION-SPECTROMETRY, Measurement techniques, 39(8), 1996, pp. 879-882
Citations number
6
Categorie Soggetti
Instument & Instrumentation",Engineering
Journal title
ISSN journal
05431972
Volume
39
Issue
8
Year of publication
1996
Pages
879 - 882
Database
ISI
SICI code
0543-1972(1996)39:8<879:AMOOTO>2.0.ZU;2-H
Abstract
We have obtained a quasioptimal (with respect to the maximin criterion ), background-invariant rule for observation of analytical signals fro m traces of chemical elements using atomic emission spectrometry data. We introduce a dimensionless analytical parameter, and use its depend ence on the concentration of the chemical element in the analyte objec t for determination of lanthanum in aqueous solutions on an inductivel y coupled plasma atomic emission spectrometer. We present estimates of the accuracy of the determination.