Gm. Bashin et At. Savichev, ASYMPTOTICALLY MAXIMIN OBSERVATION OF TRACES OF CHEMICAL-ELEMENTS FROM ANALYTICAL SIGNALS OF INDUCTIVELY-COUPLED PLASMA-ATOMIC EMISSION-SPECTROMETRY, Measurement techniques, 39(8), 1996, pp. 879-882
We have obtained a quasioptimal (with respect to the maximin criterion
), background-invariant rule for observation of analytical signals fro
m traces of chemical elements using atomic emission spectrometry data.
We introduce a dimensionless analytical parameter, and use its depend
ence on the concentration of the chemical element in the analyte objec
t for determination of lanthanum in aqueous solutions on an inductivel
y coupled plasma atomic emission spectrometer. We present estimates of
the accuracy of the determination.