Photo-activation processes for electroless plating have the potential
for linewidth resolution on a scale of the order of 10 mu m or less, d
epending on the substrate surface morphology and plating conditions. T
his work presents the first AFM and linewidth resolution study of insu
lating substrates selectively activated using a purpose-built KrCl ex
cimer lamp contact mask aligner with proprietary photochemical activat
ion precursors having optimum Photoactivity at the excimer lamp wavele
ngth. The surface morphology of a photodefined activation layer on cer
amics of varying surface topography, and on highly orientated pyrolyti
c graphite (HOPG), was investigated using atomic force microscopy. The
subsequent nucleation and growth of the electroless metallisation on
96% alumina were also studied. The minimum achievable resolution of th
e subsequent electroless copper metallisations on alumina ceramic subs
trates is evaluated. (C) 1998 Elsevier Science S.A.