The chemical structure of neutral clouds in low-metallicity environmen
ts is examined, with particular emphasis on the H to H-2 and C+ to CO
transitions. We observed near-IR H-2 (1, 0) S(1), (2, 1) S(1), and (5,
3) 0(3) lines and the (CO)-C-12 J = 1 --> 0 line from 30 Doradus and
N159/N160 in the Large Magellanic Cloud and from DEM S 16, DEM S 37, a
nd LI-SMC 36 in the Small Magellanic Cloud. We find that the H, emissi
on is UV-excited and that tweak) CO emission always exists tin our sur
veyed regions) toward positions where H-2 and [C II] emission have bee
n detected. Using a PDR code and a radiative transfer code, we simulat
e the emission of line radiation from spherical clouds and from large
planar clouds. Because [C II] emission and H-2 emission arise on the s
urface of the cloud and because the lines are optically thin, these li
nes are not affected by changes in the relative sizes of the neutral c
loud and the GO-bearing core, while the optically thick CO emission ca
n be strongly affected. The sizes of clouds are estimated by measuring
the deviation of CO emission strength from that predicted by a planar
cloud model of a given size. The average cloud column density, and th
erefore its size, increases as the metallicity decreases. Our result a
grees with the photoionization-regulated star formation theory of McKe
e.