The clustering of boron in highly boron-doped silicon and its influenc
e on electrical deactivation are reported. Highly boron-doped crystall
ine silicon was fabricated as a starting material by solid phase epita
xy of boron-doped amorphous silicon films. Boron can be supersaturated
in the crystallized samples annealed at a low temperature of about 60
0 degrees C. A lot of precipitates, containing clustered boron, were o
bserved in the samples annealed at high temperatures of about 1000 deg
rees C. The chemical states and the atomic configuration of boron in s
amples annealed at various temperatures corresponded to the electrical
deactivation of boron.