C. Andronache et Wl. Chameides, INTERACTIONS BETWEEN SULFUR AND SOOT EMISSIONS FROM AIRCRAFT AND THEIR ROLE IN CONTRAIL FORMATION 2 - DEVELOPMENT, J GEO RES-A, 103(D9), 1998, pp. 10787-10802
A numerical box model of the time evolution of key gaseous and aerosol
species in an expanding plume of a subsonic aircraft is developed to
investigate the effects of aircraft emissions on the characteristics o
f contrails. The model simulates the formation and growth of new parti
cles from H2SO4 and H2O and the growth of activated soot particles. Co
agulation, dilution, and interaction with gaseous species are included
. The evidence of contrail formation is determined by the condensed wa
ter concentration, using a visibility threshold of 10(-5) kg m(-3). Th
e model simulates formation of large concentrations of H2SO4-H2O parti
cles with radii in the range similar to 1-10 nm. The number concentrat
ion and the rate of growth of these particles is dependent on the sulf
ur emissions. We find that for a given initial concentration of soot p
articles and ambient conditions the sensitivity of contrail properties
to fuel sulfur content is small for typical emission indices (0.1-1 g
kg(-1)). For larger sulfur emissions and favorable conversion of sulf
ur into H2SO4 the calculations show a slight impact of sulfur on contr
ail properties, such as lifetime, onset, and threshold temperature. Th
e magnitude of this influence is generally smaller than the variations
caused by uncertainties in the mass accommodation coefficient of sulf
ur species on soot surface, entrainment rate of ambient air into the p
lume, soot emissions, and atmosphere parameters at flight altitude.