PHYSICAL-PROPERTIES OF STRATOSPHERIC CLOUDS DURING THE ANTARCTIC WINTER OF 1995

Lidar observations collected during winter 1995 at McMurdo Station, An tarctica (78 degrees S-167 degrees E), are analyzed to determine polar stratospheric cloud (PSC) physical properties. A scheme to infer PSC phase from lidar depolarization and backscatter profiles is presented. Interpretation is supported by collocated temperature soundings and b y isentropic back trajectories. The analysis shows that first appearan ce of PSC is consistent with frozen sulfates, mixing with liquid terna ry solutions (H2SO4-HNO3-H2O) when temperature lowers. Finally, solids consistent with HNO3 mixing ratios form as mixed phases first, then f ollowed by full solid phases. Mixed phases (i.e., coexisting solid and liquid aerosols) are detected during the whole winter. While mixed ph ase PSCs form particularly in the altitude range 15-20 km and are the last to disappear, full solid phases are mainly observed above 20 km a nd last until the end of August. Mixed phases possess the largest PSC surface areas and, as a result of selective growth, can reach large, f ast settling sizes. The considerable denitrification and halogen activ ation observed in the Antarctic lower stratosphere, where the ozone ho le takes place, appears to be well correlated with the action of this kind of PSC.