Wj. Mcneil et al., DIFFERENTIAL ABLATION OF COSMIC DUST AND IMPLICATIONS FOR THE RELATIVE ABUNDANCES OF ATMOSPHERIC METALS, J GEO RES-A, 103(D9), 1998, pp. 10899-10911
Although it is generally accepted that extraterrestrial material is th
e source of metals in the upper atmosphere, the relative abundances of
mesospheric metal atoms and ions present us with a conundrum. Lidar o
bservations have consistently shown that the abundances of neutral met
als in the atmosphere and the abundances of these metals in the meteor
ic material that falls to Earth are significantly disproportionate. Th
e column density of neutral sodium is perhaps 2 orders of magnitude la
rger than that of calcium, while the abundances in meteorites are appr
oximately equal. By contrast, ion mass spectroscopy has shown that the
abundances of the meteoric ions match reasonably well those in the me
teorites. We present here a model that attempts to address these discr
epancies. At the heart of the model is the concept of differential abl
ation, which suggests that more volatile metals sublimate earlier in t
he descent of a cosmic dust particle than do the less volatile compone
nts. We model three different meteoric metals: sodium, magnesium, and
calcium. Results suggest that sodium ablates to a greater extent than
does calcium and that it ablates at a substantially higher altitude. D
eposition at lower altitudes leads to more rapid conversion of the ato
mic calcium into complexes through three-body reactions. Thus the depl
etion of calcium arises from both a decrease in deposition and an incr
ease in the rate of removal of that which is deposited. We examine the
behavior of the model in several respects, comparing predicted result
s with measurements and finding reasonable agreement. We argue that th
e success of this model indicates that differential ablation is a key
factor in the determination of the relative abundances of meteoric met
als in the mesosphere.