Anisotropic chemical etching of monocrystalline silicon in KOH aqueous
solution is investigated. The atomic scale model proposed is based on
the influence of the OH group on chemical bonds. Etch rate and activa
tion energies are calculated and extended to the complete etch rate po
lar diagram and compared to available experimental data. Finally, an a
nalytical description of etch rate ratios is proposed. (C) 1997 Elsevi
er Science Ltd.