Atomic hydrogen (H) generated by a simple thermal cracker source has
been used to efficiently clean the polar surfaces of several III-V sem
iconductors at temperatures significantly lower than those normally re
quired for oxide desorption. The process of atomic hydrogen cleaning (
AHC) is demonstrated for the preparation of the (001) and (111)A surfa
ces of InAs, and the InSb(001) and GaSb(001) surfaces. Both the substr
ate anneal temperature and the required H dose vary for the different
materials, but in all cases clean, well-ordered surfaces can be produ
ced, as determined by low energy electron diffraction (LEED) and Auger
electron spectroscopy (AES). It is found that both the InAs and GaSb
surfaces carl be cleaned with H exposures at a specific temperature (
as low as 470 K for GaSb and 700 K for InAs); however, for InSb it is
also necessary to supply an Sb, flux from a Knudsen cell to avoid deco
mposition of the surface. High resolution electron energy loss spectro
scopy (HREELS) has been used to monitor the surface plasmon excitation
s in these doped materials to measure the carrier concentration in the
near-surface region. It is found that no measurable passivation of do
nors or accepters occurs in either the n-type or p-type materials stud
ied. In addition, and in contrast to ion sputtering procedures, no def
ect induced increase in the carrier concentration occurs as a result o
f atomic hydrogen cleaning. (C) 1998 Elsevier Science B.V. All rights
reserved.