NICKEL-CATALYZED SILANE REDUCTIONS OF ALPHA,BETA-UNSATURATED KETONES AND NITRILES

Authors
BOUDJOUK P CHOI SB HAUCK BJ RAJKUMAR AB
Citation
P. Boudjouk et al., NICKEL-CATALYZED SILANE REDUCTIONS OF ALPHA,BETA-UNSATURATED KETONES AND NITRILES, Tetrahedron letters, 39(23), 1998, pp. 3951-3952
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
23
Year of publication
1998
Pages
3951 - 3952
Database
ISI
SICI code
0040-4039(1998)39:23<3951:NSROAK>2.0.ZU;2-#
Abstract
Activated nickel, produced by the ultrasound-promoted reduction of nic kel iodide with lithium, catalyzes the 1,4 addition of phenylsilane to alpha, beta-unsaturated ketones and alpha, beta-unsaturated nitriles to give, after hydrolysis, high yields of the products of 1, 2 hydroge nation. (C) 1998 Elsevier Science Ltd. All rights reserved.