THE EFFICIENT STEREOSELECTIVE SYNTHESIS OF Z-VINYLSILANES THROUGH THESUZUKI-MIYAURA COUPLING OF Z(ALPHA-SILYLVINYL)BORINATES

Authors
SODERQUIST JA LEON G
Citation
Ja. Soderquist et G. Leon, THE EFFICIENT STEREOSELECTIVE SYNTHESIS OF Z-VINYLSILANES THROUGH THESUZUKI-MIYAURA COUPLING OF Z(ALPHA-SILYLVINYL)BORINATES, Tetrahedron letters, 39(23), 1998, pp. 3989-3990
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
23
Year of publication
1998
Pages
3989 - 3990
Database
ISI
SICI code
0040-4039(1998)39:23<3989:TESSOZ>2.0.ZU;2-K
Abstract
Air-stable Z-(alpha-silylvinyl)borinates (2), easily prepared in a hyd roboration-oxidation sequence from 1 provide a particularly effective route to Z-vinylsilanes (3, 59-97%) through Suzuki-Miyaura coupling. ( C) 1998 Elsevier Science Ltd. All rights reserved.