VIBRATIONAL-RELAXATION OF HCL(V=1) IN HCL CO2 AND HCL/CO2/ARGON GASEOUS-MIXTURES/

Authors
LAMP JA SCHRAMM B
Citation
Ja. Lamp et B. Schramm, VIBRATIONAL-RELAXATION OF HCL(V=1) IN HCL CO2 AND HCL/CO2/ARGON GASEOUS-MIXTURES/, Chemical physics letters, 288(1), 1998, pp. 83-88
Citations number
5
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
288
Issue
1
Year of publication
1998
Pages
83 - 88
Database
ISI
SICI code
0009-2614(1998)288:1<83:VOHIHC>2.0.ZU;2-T
Abstract
Vibrational relaxation of HCl(nu = 1) in HCl/CO2 and HCl/CO2/Ar gaseou s mixtures has been measured at room temperature (296K) by the laser-i nduced fluorescence (LIF) technique. The observed rate constants are s maller than described in the literature. All measured fluorescence cur ves are successfully recalculated with the rate constants evaluated in this work. Argon as a buffer gas raises the fluorescence intensity, w ithout an influence on the rate constants. (C) 1998 Elsevier Science B .V. All rights reserved.