A STEREOSELECTIVE SYNTHESIS OF METHYL BETA-C-LACTOSIDE THROUGH THE TETHER APPROACH

Authors
RUBINSTENN G MALLET JM SINAY P
Citation
G. Rubinstenn et al., A STEREOSELECTIVE SYNTHESIS OF METHYL BETA-C-LACTOSIDE THROUGH THE TETHER APPROACH, Tetrahedron letters, 39(22), 1998, pp. 3697-3700
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
22
Year of publication
1998
Pages
3697 - 3700
Database
ISI
SICI code
0040-4039(1998)39:22<3697:ASSOMB>2.0.ZU;2-E
Abstract
Methyl beta-C-lactoside (beta-D-Galp-C-(1-->4)-beta-Glcp-OMe) is stere oselectively synthesized by radical coupling of phenyl Se-beta-D-galac topyranoside 5 onto exo-methylene-sugar 4, which are temporarily conne cted through a silaketal tether. (C) 1998 Elsevier Science Ltd. All ri ghts reserved.