PREPARATION OF ALLYLSILANES BY THE OLEFINATION OF CARBONYL-COMPOUNDS USING BETA-SILYLTHIOACETALS

Authors
TAKEDA T WATANABE M RAHIM MA FUJIWARA T
Citation
T. Takeda et al., PREPARATION OF ALLYLSILANES BY THE OLEFINATION OF CARBONYL-COMPOUNDS USING BETA-SILYLTHIOACETALS, Tetrahedron letters, 39(22), 1998, pp. 3753-3756
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
22
Year of publication
1998
Pages
3753 - 3756
Database
ISI
SICI code
0040-4039(1998)39:22<3753:POABTO>2.0.ZU;2-0
Abstract
Titanocene(II)-promoted olefination of various carbonyl compounds usin g 1,1-bis(phenylthio)-2-triorganosilylethanes gave allylsilanes in goo d yields, gamma-Alkoxy and alkylthio group substituted allylsilanes we re also obtained by using carboxylic eaters and thiolesters, respectiv ely. (C) 1998 Elsevier Science Ltd. All rights reserved.