MOLECULAR RECEPTOR FOR BINDING QUATERNARY AMMONIUM-SALTS AND A LARGE ANION EFFECT ON THE COMPLEXATION

Citation
Ks. Jeong et al., MOLECULAR RECEPTOR FOR BINDING QUATERNARY AMMONIUM-SALTS AND A LARGE ANION EFFECT ON THE COMPLEXATION, Tetrahedron letters, 39(22), 1998, pp. 3779-3782
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
39
Issue
22
Year of publication
1998
Pages
3779 - 3782
Database
ISI
SICI code
0040-4039(1998)39:22<3779:MRFBQA>2.0.ZU;2-M
Abstract
An acyclic receptor 1 with a binding cavity surrounded by electron-ric h aryl surfaces has been synthesized for binding quaternary ammonium s alts through cation-pi interactions. The association constants of the receptor 1 with salts in CDCl3 depend on the anions due to the hydroge n bonds between the exchangeable protons in the receptor 1 and anions. (C) 1998 Elsevier Science Ltd. All rights reserved.