We developed thin film retardation plates of silica glass which work w
ith normally incident lights at a wavelength as short as 300 nm. By de
positing silica from an oblique direction (70 degrees from the substra
te surface-normal) onto substrates, unique microscopic columnar struct
ures were obtained. The columns of approximately 20 nm in diameter wer
e inclined to the deposition direction which cause birefringence. Alth
ough obliquely deposited thin films often become opaque because of coa
lescence of the columns enhanced by absorbing moisture after the depos
ition processes, the opacity was suppressed using stacked structures o
f obliquely deposited and normally deposited layers.