OXIDATION OF AMINO ESTERS TO IMINE COMPLEXES WITH CHIRAL HIGH-VALENT OXORUTHENIUM PORPHYRINS

Authors
MORICE C LEMAUX P MOINET C SIMONNEAUX G
Citation
C. Morice et al., OXIDATION OF AMINO ESTERS TO IMINE COMPLEXES WITH CHIRAL HIGH-VALENT OXORUTHENIUM PORPHYRINS, Inorganica Chimica Acta, 273(1-2), 1998, pp. 142-150
Citations number
47
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
273
Issue
1-2
Year of publication
1998
Pages
142 - 150
Database
ISI
SICI code
0020-1693(1998)273:1-2<142:OOAETI>2.0.ZU;2-1
Abstract
The chemical oxidation of amino esters by high valent oxoruthenium por phyrins to give mixed ligated imino ester/amino ester ruthenium( II) p orphyrin complexes is described. The same complexes were also obtained by anodic oxidation at a constant potential of the corresponding bis( amino ester) ruthenium(II) porphyrins. The electrochemical data were f ound consistent with a mechanism involving a Ru(IV) intermediate forme d by disproportionation of a Ru(III) species. (C) 1998 Elsevier Scienc e S.A. All rights reserved.