A CYANO-BRIDGED IRON(III) LINEAR-CHAIN WITH ALTERNATING FE(CN)(6)-FE(CYCLAM) (CYCLAM = 1,4,8,11-TETRAAZACYCLODECANE) UNITS AND UNEXPECTED FERROMAGNETIC BEHAVIOR
E. Colacio et al., A CYANO-BRIDGED IRON(III) LINEAR-CHAIN WITH ALTERNATING FE(CN)(6)-FE(CYCLAM) (CYCLAM = 1,4,8,11-TETRAAZACYCLODECANE) UNITS AND UNEXPECTED FERROMAGNETIC BEHAVIOR, Chemical communications, (10), 1998, pp. 1071-1072
The X-ray crystal structure and magnetic properties of a cyano-bridged
iron(III) linear chain containing alternating iron sites and unexpect
ed ferromagnetic behaviour, justified on the basis of the axial distor
tion from regular octahedral geometry of one of the iron(In) ions, are
reported.