QUANTITATIVE FORMATION OF THE INTERMEDIATE OF ALKENE INSERTION IN THECOPOLYMERIZATION OF P-METHYLSTYRENE AND CARBON-MONOXIDE CATALYZED BY [(PR(I)DAB)PD(ME)(NCME)]-(BAR4)
C. Carfagna et al., QUANTITATIVE FORMATION OF THE INTERMEDIATE OF ALKENE INSERTION IN THECOPOLYMERIZATION OF P-METHYLSTYRENE AND CARBON-MONOXIDE CATALYZED BY [(PR(I)DAB)PD(ME)(NCME)]-(BAR4), Chemical communications, (10), 1998, pp. 1113-1114
The intermediate after the first CO and p-methylstyrene insertion in t
he chain growth process of the copolymerization of these monomers has
been quantitatively obtained from (i)DAB)Pd(Me)(NCMe)](+)[{3,5-(CF3)(2
)C6H3}(4)B](-) in CHCl3 at 20 degrees C.