FROM HELICATE TO INFINITE COORDINATION POLYMER - CRYSTAL AND MOLECULAR-STRUCTURES OF SILVER(I) COMPLEXES OF READILY PREPARED DI-SCHIFF BASES

Authors
BOWYER PK PORTER KA RAE AD WILLIS AC WILD SB
Citation
Pk. Bowyer et al., FROM HELICATE TO INFINITE COORDINATION POLYMER - CRYSTAL AND MOLECULAR-STRUCTURES OF SILVER(I) COMPLEXES OF READILY PREPARED DI-SCHIFF BASES, Chemical communications, (10), 1998, pp. 1153-1154
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
10
Year of publication
1998
Pages
1153 - 1154
Database
ISI
SICI code
1359-7345(1998):10<1153:FHTICP>2.0.ZU;2-U
Abstract
The readily prepared di-Schiff base of pyridine-2-aldehyde and ethane- 1,2-diamine 1 reacts with silver(I) tetrafluoroborate to form by self- assembly the double-stranded D-2-helicate (+/-)-[Ag(2)1(2)](BF4)(2); t he corresponding Schiff base of (1R,2R)-cyclohexane-1,2-diamine [(R,R) -2] reacts with silver(I) nitrate to produce the homochiral single-str anded C-2-coordination polymer M-{[Ag{(R,R)-2}]NO3 . 2H(2)O}(infinity) .