STRUCTURAL EXPLORATION OF HYDROXO BRIDGED TRIAMINE COMPLEXES OF ZINC(II)

Authors
MONDAL A MOSTAFA G GHOSH A CHAUDHURI NR WONG WT
Citation
A. Mondal et al., STRUCTURAL EXPLORATION OF HYDROXO BRIDGED TRIAMINE COMPLEXES OF ZINC(II), Polyhedron, 17(8), 1998, pp. 1217-1221
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
17
Issue
8
Year of publication
1998
Pages
1217 - 1221
Database
ISI
SICI code
0277-5387(1998)17:8<1217:SEOHBT>2.0.ZU;2-9
Abstract
Single crystal structure of [Zn-2(dpt)(2)(mu-OH)](ClO4)(3) (dpt = bis( 3-aminopropyl) amine) shows that two units of Zn(dpt) are bridged by o xygen atom of the hydroxo group. Each Zn-atom possesses distorted tetr ahedral geometry. Analogous complexes [Zn2L2(mu-OH)](ClO4)(3) [L = bis (3-aminopropyl) methylamine(medpt), bis (2-aminoethyl)methylamine(medi en)] have been synthesised. (C) 1998 Elsevier Science Ltd. All rights reserved.