ELECTRON-TRANSFER MECHANISMS - A MECHANISTIC CHANGEOVER INDUCED BY ANINTRAMOLECULAR SPACER IN A MODEL REACTION OF THE NH3 C2H4-CENTER-DOT+PAIR/

Authors
REDDY AC SASTRY GN SHAIK S
Citation
Ac. Reddy et al., ELECTRON-TRANSFER MECHANISMS - A MECHANISTIC CHANGEOVER INDUCED BY ANINTRAMOLECULAR SPACER IN A MODEL REACTION OF THE NH3 C2H4-CENTER-DOT+PAIR/, Perkin transactions. 2, (9), 1995, pp. 1717-1719
Citations number
30
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
9
Year of publication
1995
Pages
1717 - 1719
Database
ISI
SICI code
0300-9580(1995):9<1717:EM-AMC>2.0.ZU;2-T
Abstract
Computational evidence is reported for a reversal in the type of an el ectron transfer (ET) mechanism, induced by an intramolecular linkage o f the donor (amine) and acceptor (cation radical) moieties via a singl e -CH2(-)spacer. An isotope effect probe is suggested to detect this m echanistic changeover.