NICKEL(II) COMPLEXES OF N-HETEROCYCLIC CARBENES

Authors
HERRMANN WA GERSTBERGER G SPIEGLER M
Citation
Wa. Herrmann et al., NICKEL(II) COMPLEXES OF N-HETEROCYCLIC CARBENES, Organometallics, 16(10), 1997, pp. 2209-2212
Citations number
47
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
10
Year of publication
1997
Pages
2209 - 2212
Database
ISI
SICI code
0276-7333(1997)16:10<2209:NCONC>2.0.ZU;2-O
Abstract
Nickel(II) complexes with N-heterocyclic carbenes are accessible throu gh substitution of triphenylphosphine in NiX2(PPh3)(2) (X = Cl, Br) by the free carbenes or by in situ deprotonation of the corresponding az olium salts with Ni(OAc)(2) as the starting material. H-1 and C-13 NMR as well as X-ray crystallographic data are discussed.