CATALYTIC DECOMPOSITION OF ALKYL CHLOROFORMATES BY HEXABUTYLGUANIDINIUM CHLORIDE

Authors
FOULON F FIXARI B PICQ D LEPERCHEC P
Citation
F. Foulon et al., CATALYTIC DECOMPOSITION OF ALKYL CHLOROFORMATES BY HEXABUTYLGUANIDINIUM CHLORIDE, Tetrahedron letters, 38(19), 1997, pp. 3387-3390
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
19
Year of publication
1997
Pages
3387 - 3390
Database
ISI
SICI code
0040-4039(1997)38:19<3387:CDOACB>2.0.ZU;2-T
Abstract
Hexabutylguanidinium chloride (0.5 molar %) efficiently decomposes alk yl chloroformates into Chlorides, with low alkenes formation, via a S( N)2 mechanism as demonstrated from, substituents effects and asymmetri c chloride synthesis. (C) 1997 Elsevier Science Ltd.