INFLUENCE OF THE LIGAND ON THE GAS-PHASE REACTIVITY OF IRON COMPLEXESFE(CX)(-2)() (X=O, N, S, F2, CL)

Authors
CAPRON L MESTDAGH H ROLANDO C
Citation
L. Capron et al., INFLUENCE OF THE LIGAND ON THE GAS-PHASE REACTIVITY OF IRON COMPLEXESFE(CX)(-2)() (X=O, N, S, F2, CL), Tetrahedron letters, 38(19), 1997, pp. 3401-3404
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
19
Year of publication
1997
Pages
3401 - 3404
Database
ISI
SICI code
0040-4039(1997)38:19<3401:IOTLOT>2.0.ZU;2-Q
Abstract
Ion-molecule reactivities of different one-carbon ligand complexes Fe( CX)(+) with oxygen and allyl chloride appeared strongly dependent on t he nature and binding energy of the ligand. With oxygen ligand oxidati on occurred for X = O, S. With allyl chloride coupling products were o bserved in the only case of the Fe(CS)(+) complex. (C) 1997 Published by Elsevier Science Ltd.