Tr. Gentry et al., ACCELERATED TEST METHODS TO DETERMINE THE LONG-TERM BEHAVIOR OF COMPOSITE HIGHWAY STRUCTURES SUBJECT TO ENVIRONMENTAL LOADING, Journal of composites technology & research, 20(1), 1998, pp. 38-50
Research on fiber-reinforced plastic composites has explored the effec
ts of selected aqueous environments on the mechanical and physical pro
perties of these composites. The composite materials tested were produ
ced using the pultrusion process. Resins included in the study were po
lyester and vinylester. Fibers included were E-glass, carbon, and aram
id. Environments considered were air, deionized water, acetic acid at
two concentrations, and ammonia at two concentrations. Temperatures co
nsidered were room temperature, 50 and 80 degrees C. Mechanical testin
g included tension, flexure, and short beam shear tests. Weight loss,
thermogravimetric, and calorimetric measurements were made to determin
e whether degradation was taking place in the fiber or matrix phases o
f the composite. Accelerating factors for the various environments wer
e calculated using the framework outlined in ASTM E 632, Standard Prac
tice for Developing Accelerated Tests to Aid in the Prediction of the
Service Life of Building Components and Materials. It was observed tha
t a combination of weight loss and thermogravimetric measurements are
useful in determining whether degradation in the composite is due to f
iber or matrix degradation. Trends in weight loss closely parallel los
s of mechanical properties in polyester/glass rods.