M. Gargouri et al., CONDUCTIVITY AND STRUCTURAL STUDIES OF NEW MIXED POTASSIUM HYDROGENO-SULFATE SELENATE KH(SO4)(0.8)(SEO4)(0.2), Physica status solidi. b, Basic research, 207(1), 1998, pp. 289-298
Single crystals and polycrystalline samples of KH(SO4)(0.8)(SeO4)(0.2)
were obtained by slow evaporation at 300 K. The samples were characte
rized by X-ray diffraction, examined by Raman vibrational spectroscopy
and impedance spectroscopy technique. At high temperatures, no phase
transition leading to a superionic phase was found. KH(SO4)(0.8)(SeO4)
(0.2) is characterized by a medium conductivity sigma approximate to 3
x 10(-8) Omega(-1) cm(-1) and an activation energy E-a approximate to
0.5 eV.