Tunnel junctions comprised of two magnetic metal layers separated by a
thin insulating oxide layer have been prepared by reactive sputtering
onto thermally oxidized (100) silicon wafers at room temperature. The
magnetic layers (thicknesses similar to 30-50 nm) consisted of thin f
ilms of Co, Fe, and/or CoFe and the oxide barriers (thicknesses in the
range 2-10 nm) included CoO, MgO, HfO2, and SiO2. The barriers were p
repared by de reactive sputtering from pure metal sources in mixed oxy
gen-argon atmospheres or by rf sputtering from oxide targets. Transmis
sion electron microscopy in the cross-sectional geometry was used in t
his study to characterize the tunnel junction microstructure. Barriers
of CoO and MgO were invariably polycrystalline with many crystallites
extending across the entire barrier thickness, whereas barriers of Si
O2 and HfO2 appeared to be amorphous. Although grain boundary diffusio
n has been proposed as a possible mechanism for providing shorts or ''
pinholes'' between the magnetic electrodes, it was significant that bo
th HfO, (amorphous) and MgO (polycrystalline) showed high magnetoresis
tive response at low temperature. (C) 1998 American Institute of Physi
cs.