UABIS(HEXAFLUOROACETYLACETONATO-O,O')MANGANESE(II) MONOHYDRATE

Authors
DICKMAN MH
Citation
Mh. Dickman, UABIS(HEXAFLUOROACETYLACETONATO-O,O')MANGANESE(II) MONOHYDRATE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 402-404
Citations number
11
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
4
Pages
402 - 404
Database
ISI
SICI code
0108-2701(1997)53:<402:UM>2.0.ZU;2-G
Abstract
In the crystals of 5-hexafluoropentane-2,4-dionato-O,O')manganese(ll) monohydrate, [Mn(C5HF6O2)(2)(H2O)(2)].H2O, the Mn atom and all three w ater molecules lie on a crystallographic mirror plane. Two of the wate r molecules are coordinated to the Mn atom in a trans geometry and the third links the structure into hydrogen-bonded sheets. The two planar hexafluoroacetylacetonato ligands related by the mirror plane form a dihedral angle of 41.6(2)degrees with one another. One CF3 group displ ayed significant disorder.