IDO-BIS[DICYCLOHEXYLPHOSPHINE(TRICARBONYL)RHENIUM]

Authors
FLORKE U HAUPT HJ
Citation
U. Florke et Hj. Haupt, IDO-BIS[DICYCLOHEXYLPHOSPHINE(TRICARBONYL)RHENIUM], Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 404-406
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
4
Pages
404 - 406
Database
ISI
SICI code
0108-2701(1997)53:<404:I>2.0.ZU;2-E
Abstract
The title compound, hexacarbonyl-1 kappa(3) C,2 kappa(3)C-mu-dicyclohe xylphosphido-1:2 kappa(2)P-bis(dicyclohexylphosphine)-1 kappa P,2 kapp a P-mu-hydrido-dirhenium(Re-Re), [Re2H(C12H22-P)(C12H23P)(2)(CO)(6)], has an Re--Re bond length of 3.2185 (8) Angstrom which is symmetricall y bridged by a H and a P atom. Two terminal PH(C6H11)(2) ligands adopt cis positions with respect to the phosphido bridge and have a mutuall y trans configuration.