TETRAPHENYLPHOSPHONIUM (HYDROGENSULFIDO-S)TRISULFIDOTUNGSTATE(VI)

Authors
PARVEZ M BOORMAN PM WANG MP
Citation
M. Parvez et al., TETRAPHENYLPHOSPHONIUM (HYDROGENSULFIDO-S)TRISULFIDOTUNGSTATE(VI), Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 413-414
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
4
Pages
413 - 414
Database
ISI
SICI code
0108-2701(1997)53:<413:T(>2.0.ZU;2-8
Abstract
The cations and anions of the title compound, [(C6H5)(4)P][W(HS)S-3], are separated by normal van der Waals distances. The ions each Lie on (4) over bar sites such that the H atom of the anion is disordered ove r four sites with 0.25 occupancies. The W-S distances in the anion are 2.171 (2) Angstrom, with S-W-S angles of 108.1 (1) and 112.4 (2)degre es. In the cation, identical P-C distances of 1.793(6) Angstrom are ob served, with C-P-C angles of 106.3 (4) and 111.1(2)degrees.