Ground water flow and transport processes in fractured porous rocks pr
esent special challenges for obtaining representative samples. Designi
ng appropriate monitoring programs for these systems requires an asses
sment of spatial and temporal variability (1) to define representative
ness, and (2) to determine the most efficient and cost-effective metho
ds for obtaining representative samples. Gas tracer studies, borehole
tests, and geochemical sampling conducted at a fractured rock site in
east Tennessee indicate large spatial and temporal variations in trans
port processes. Ground water flow as indicated by helium tracers moves
predominantly along strike, perpendicular to hydraulic gradients exce
pt during storm events, demonstrating temporal variability in transpor
t directions. Distinct vertical changes in water chemistry encountered
in multilevel wells are indicative of discrete transport pathways in
a poorly mixed system. Comparison of samples obtained from standard sc
reened wells and multilevel wells show that screened wells mask these
vertical variations in ground water composition and miss important tra
nsport pathways. Experimental results demonstrate the need for adequat
e characterization of spatial and temporal variations for appropriate
placement and construction of monitoring wells, timing of ground water
monitoring, and evaluation of exposure risk and contaminant flux in s
upport of remedial decision making.