T. Kingetsu et al., KINETICS OF CRISTOBALITE GROWTH ON POLYCRYSTALLINE SIC FILM STUDIED USING HIGH-TEMPERATURE IN-SITU X-RAY-DIFFRACTOMETRY, Materials research bulletin, 33(5), 1998, pp. 731-738
The kinetics of cristobalite growth on polycrystalline beta-SiC films
at 1803 and 1873 K were investigated. Sample films were synthesized on
graphite strips via chemical vapor deposition and heated in air by th
eir electric resistance. It was demonstrated that in situ X-ray diffra
ctometry using imaging plate was useful for analyzing the growth of th
e oxide crystals with the coexistence of amorphous silica. The kinetic
s were found to obey parabolic laws. This is consistent with oxidation
kinetics of SiC reported earlier. (C) 1998 Elsevier Science Ltd.