A 4-OXIDATION-STATE FAMILY OF COORDINATED CARBON - THE FIRST ISOLABLEAND CRYSTALLOGRAPHICALLY CHARACTERIZED TRIRADICAL [M]-C-4-[M](3+)

Authors
GUILLEMOT M TOUPET L LAPINTE C
Citation
M. Guillemot et al., A 4-OXIDATION-STATE FAMILY OF COORDINATED CARBON - THE FIRST ISOLABLEAND CRYSTALLOGRAPHICALLY CHARACTERIZED TRIRADICAL [M]-C-4-[M](3+), Organometallics, 17(10), 1998, pp. 1928-1930
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
10
Year of publication
1998
Pages
1928 - 1930
Database
ISI
SICI code
0276-7333(1998)17:10<1928:A4FOCC>2.0.ZU;2-0
Abstract
The deep blue complex [Cp(dippe)Fe(mu-C-4)-Fe(dippe)Cp*](3+)[PF6](-)( 3) (4(3+)[PF6](-)(3)) was prepared by a cascade of three successive on e-electron oxidations of the neutral complex Cp(dippe)Fe(mu-C-4)Fe(di ppe)Cp (4). This unprecedented trication was characterized by X-ray m ethods, and its triradical structure was established on the basis of M ossbauer, near-IR, and ESR spectroscopy.