A study of the multiple minima problem was performed for a simple case
using simulations. The test case was static (usually ex-situ) spectro
scopic ellipsometry of thick dielectric films on crystalline silicon s
ubstrates taken at high sensitivity conditions near the s-wave antiref
lection angle-of-incidence (AOI). Analysis of the data was performed u
sing the Levenberg-Marquardt algorithm with the unbiased tan Psi and c
os Delta estimator. A large number of minima were observed on both sid
es of the main minimum, albeit with larger values of the error functio
n. Moreover, data simulated at additional AOIs and/or at additional wa
velengths showed an even higher number of minima. Three ways to overco
me this problem are suggested: using another estimator, reducing the s
ensitivity of the data or performing a grid search. (C) 1998 Elsevier
Science S.A.