A FIRST EXAMPLE OF MACROMOLECULAR TI(IV) LEWIS-ACID IN THE CATALYTIC ENANTIOSELECTIVE MUKAIYAMA REACTION

Authors
MANDOLI A PINI D ORLANDI S MAZZINI F SALVADORI P
Citation
A. Mandoli et al., A FIRST EXAMPLE OF MACROMOLECULAR TI(IV) LEWIS-ACID IN THE CATALYTIC ENANTIOSELECTIVE MUKAIYAMA REACTION, Tetrahedron : asymmetry, 9(9), 1998, pp. 1479-1482
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
9
Year of publication
1998
Pages
1479 - 1482
Database
ISI
SICI code
0957-4166(1998)9:9<1479:AFEOMT>2.0.ZU;2-D
Abstract
The preparation and characterization of a soluble copolymer P1 between styrene, divinylbenzene (DVB) and the enantiomerically pure salicylal dimine ligand 3c is described. The Lewis acid prepared from this macro molecular chiral ligand and Ti((OPr)-Pr-i)(4) has been used in the cat alytic Mukaiyama reaction to afford benzyl (R)-3-hydroxy-3-phenylpropa noate 7. (C) 1998 Elsevier Science Ltd. All rights reserved.