EXPERIMENTAL INVESTIGATION AND THERMODYNAMIC CALCULATION OF THE AL-MG-ZN SYSTEM

On the basis of a critical assessment, experimental investigations by EPMA on ternary Al-Mg-Zn alloys were specifically performed to provide missing data of the ternary solubilities of the AI-Mg and Mg-Zn phase s as well as to improve the knowledge of the extensions of the homogen eity ranges of the ternary tau- and Phi-phases. A thermodynamic descri ption for the Al-Mg-Zn system was obtained taking into account those e xperimental data together with constitutional, thermodynamic and cryst allographic literature information. The binary intermetallic phases ar e modelled to have ternary solubilities. The ternary tau-phase is mode lled according to its crystal structure with cubic symmetry as (Mg)(26 )(Mg, Al)(6)(Al, Zn, Mg)(48)(Al)(1) in the compound-energy-formalism. The Phi-phase is described by the sublattice formula Mg-6(Al, Zn)(5). (C) 1998 Elsevier Science B.V.