Ds. Krahmer et al., CONFINED QUANTUM-SYSTEMS - THE PARABOLICALLY CONFINED HYDROGEN-ATOM, Journal of physics. A, mathematical and general, 31(19), 1998, pp. 4493-4520
We investigate a hydrogen-like atom (or any other system with a Coulom
b potential) confined to a space which is bounded by a paraboloid. The
nucleus of the atom resides at the focus of the paraboloid and we req
uire the electronic wavefunction to vanish on the paraboloid. We deriv
e an exact implicit analytic solution to the problem and also explicit
analytic expressions for the wavefunctions and eigenenergies in the s
o-called strong-shift regime. We also discuss the influence of the bou
ndary on the permanent dipole moments of the eigenstates. Finally, we
investigate this system in WKB-approximation and give the Bohr-Sommerf
eld quantization rule which is different from the usual rule due to th
e new boundary condition.